MCAT Organic Chemistry Question 30: Answer and Explanation

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Question: 30

15. If the methyl groups of butane are 120° apart, as seen in a Newman projection, this molecule is in its:

  • A. highest-energy gauche form.
  • B. lowest-energy staggered form.
  • C. middle-energy eclipsed form.
  • D. highest-energy eclipsed form.

Correct Answer: C

Explanation:

In butane, the position at which the two methyl groups are 120° apart is an eclipsed conformation. This has a moderate amount of energy, although not as high as a totally eclipsed conformation in which the two methyl groups are 0° apart.

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