MCAT Organic Chemistry Question 29: Answer and Explanation

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Question: 29

14. (2R,3S)-2,3-dihydroxybutanedioic acid and (2S,3R)-2,3-dihydroxybutanedioic acid are:

I. meso compounds.

II. the same molecule.

III. enantiomers.

  • A. I only
  • B. III only
  • C. I and II only
  • D. I and III only

Correct Answer: C

Explanation:

Draw out these structures. The two names describe the same molecule, which also happens to be a meso compound because it contains a plane of symmetry. These compounds are not enantiomers because they are superimposable mirror images of one another, not nonsuperimposable mirror images. These compounds are better termed meso-2,3-dihydroxybutanedioic acid:

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