MCAT Organic Chemistry Question 151: Answer and Explanation

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Question: 151

1. IR spectroscopy is most useful for distinguishing:

  • A. double and triple bonds.
  • B. C–H bonds.
  • C. chirality of molecules.
  • D. composition of racemic mixtures.

Correct Answer: A

Explanation:

Infrared spectroscopy is most useful for distinguishing between different functional groups. Almost all organic compounds have C–H bonds, choice (B), so except for fingerprinting a compound, these absorptions are not useful. Little information about the optical properties of a compound, such as choices (C) and (D), can be obtained by IR spectroscopy.

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