MCAT General Chemistry Question 191: Answer and Explanation
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Question: 191
2. The Ksp of NaCl in water is 35.9 at 25°C. If 500 mL of 12 M NaOH(aq) and 500 mL of 12 M HCl(aq) solution both at 25°C are combined, what would best describe the resulting solution?
- A. I only
- B. III only
- C. I and II
- D. I and III
Correct Answer: A
Explanation:
A In order to participate in intermolecular hydrogen bonding, a molecule must be able to act as both a hydrogen bond donor and acceptor. In order to act as a hydrogen bond donor, a molecule must possess a hydrogen (H) atom covalently bound to a nitrogen (N), oxygen (O), or fluorine (F) atom. In order to act as a hydrogen bond acceptor, a molecule must have an oxygen, nitrogen, or fluorine atom with an unshared pair of electrons. CH3CO2H meets both of these requirements, and is therefore a valid choice. CO2 does not possess any hydrogen atoms and is therefore an invalid option. While H2S may seem like an enticing choice, sulfur is not sufficiently electronegative to produce hydrogen bonding when covalently bound to hydrogen atoms.