MCAT General Chemistry Question 164: Answer and Explanation

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Question: 164

14. After balancing the following oxidation–reduction reaction, what is the sum of the stoichiometric coefficients of all of the reactants and products?

S8 (s) + NO3- (aq) → SO32- (aq) + NO (g)

  • A. 4
  • B. 50
  • C. 91
  • D. 115

Correct Answer: D

Explanation:

Utilize the method described earlier to balance this redox reaction. The balanced half-reactions are:

To get equal numbers of electrons in each half-reaction, the oxidation half-reaction will have to be multiplied by 3, and the reduction half-reaction will have to be multiplied by 32:

This makes the overall reaction:3S8 + 32 NO3- + 8 H2O → 24 SO32- + 32 NO + 16 H+

The sum of the stoichiometric coefficients is therefore 3 +32 + 8 + 24 + 32 + 16 = 115.

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