MCAT Biochemistry Question 80: Answer and Explanation

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Question: 80

5. For a compound to be aromatic, all of the following must be true EXCEPT:

  • A. the molecule is cyclic.
  • B. the molecule contains 4n + 2 π electrons.
  • C. the molecule contains alternating single and double bonds.
  • D. the molecule is planar.

Correct Answer: C

Explanation:

For a compound to be aromatic, it must be cyclic, planar, and conjugated, and contain 4n + 2 π electrons, where n is any integer. Conjugation requires that every atom in the ring have at least one unhybridized p-orbital. While most examples of aromatic compounds have alternating single and double bonds, compounds can be aromatic if they contain triple bonds as well; this would still permit at least one unhybridized p-orbital.

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